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A new family of “ligated” anionic initiators for the “living” polymerization of (meth)acrylic esters

✍ Scribed by P. Bayard; R. Jérôme; P. Teyssié; S. Varshney; J. S. Wang

Publisher
Springer
Year
1994
Tongue
English
Weight
207 KB
Volume
32
Category
Article
ISSN
0170-0839

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📜 SIMILAR VOLUMES

New initiator system for the anionic pol
New initiator system for the anionic polymerization of (meth)acrylates in toluene. IV. Random copolymerization of (meth)acrylates in toluene initiated by s-BuLi ligated by lithium silanolates
✍ Catherine Zune; Thomas Zundel; Philippe Dubois; Philippe Teyssié; Robert Jérôme 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 155 KB 👁 2 views

Copolymerization of binary mixtures of alkyl (meth)acrylates has been initiated in toluene by a mixed complex of lithium silanolate O(s-BuMe 2 SiOLi)O and s-BuLi (molar ratio Ͼ 21) formed in situ by reaction of s-BuLi with hexamethylcyclotrisiloxane (D 3 ). Fully acrylate and methacrylate copolymers