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Controlled Anionic Polymerization of tert -Butyl Acrylate with the tBuOK/Triisobutylaluminum (iBu 3 Al) Initiating System

✍ Scribed by Ihara, Eiji; Ikeda, Jun-ichi; Inoue, Kenzo


Book ID
126259933
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
39 KB
Volume
35
Category
Article
ISSN
0024-9297

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## Abstract In contrast to methyl 2‐lithioisobutyrate (I), __tert__‐butyl 2‐lithioisobutyrate (A) in tetrahydrofuran (THF) appears to have one form only, irrespective of concentration (0,1‐0,8 mol/L) or temperature (203–273 K). According to its relaxation characteristics, this form probably is a te