New Cationic Clathrate: Synthesis and Structure of [Si40P6]I6.5.
β Scribed by Kirill A. Kovnir; Alexei N. Uglov; Julia V. Zaikina; Andrei V. Shevelkov
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 8 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
## Abstract Upon ionization of the P~4~S~3~I~2~ molecule with Ag[Al(OR)~4~], a highly reactive sulfonium cation P~4~S~3~I^+^ is generated (NMR simulated and assigned). At β80βΒ°C this cation reacts with additional P~4~S~3~I~2~ to give either an iodophosphonium P~4~S~3~I~3~^+^ cation (NMR simulated a
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