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A Spirocyclic P—S Cage Cation: Synthesis and Formation of P7S6I2+.

✍ Scribed by Marcin Gonsior; Ingo Krossing; Eberhard Matern

Publisher
John Wiley and Sons
Year
2006
Weight
15 KB
Volume
37
Category
Article
ISSN
0931-7597

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\(\mathrm{RbVP}_{2} \mathrm{~S}_{7}\) has been obtained as black platelets by heating the elements in stoichiometric proportions at \(550^{\circ} \mathrm{C}\) under vacuum in evacuated silica tubes for 21 days. It crystallizes in the monoclinic symmetry, space group \(C 2\), with the parameters \(a=