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Formation of [Ph2P5]+, [Ph4P6]2+, and [Ph6P7]3+ Cationic Clusters by Consecutive Insertions of [Ph2P]+ into PP Bonds of the P4 Tetrahedron

✍ Scribed by Jan J. Weigand; Michael Holthausen; Roland Fröhlich


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
428 KB
Volume
48
Category
Article
ISSN
0044-8249

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Synthesis of the One-dimensional Compoun
✍ Konstantinos Chondroudis; Debojit Chakrabarty; Enos A. Axtell; Mercouri G. Kanat 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 137 KB 👁 2 views

The reaction of one equivalent of In with a molten flux of (Ph 4 P) 2 Se 5 and P 2 Se 5 (1 : 2), at 250 °C gave the (Ph 4 P)[In(P 2 Se 6 )] (I). Stoichiometric elemental synthesis at 750 °C produced the Cs 5 In(P 2 Se 6 ) 2 (II). The thin, yellow crystals of (I), and the irregular, dark orange cryst