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A New Route to Iron-Sulfur Clusters: Synthesis and Structure of [(C2H5)4N]2Fe6S6I6

โœ Scribed by Dipl.-Chem. Wolfgang Saak; Dr. Gerald Henkel; Priv.-Doz. Dr. Siegfried Pohl


Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
230 KB
Volume
23
Category
Article
ISSN
0044-8249

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โœ Michael Schur; Wolfgang Bensch ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 322 KB ๐Ÿ‘ 1 views

Reaction of elemental antimony with sulfur under mild hydrothermal conditions yielded different polysulfidoclusters of antimony. These were isolated as tetraphenylphosphonium salts [P(C 6 H 5 ) 4 ] 3 Sb 3 S 25 and [P(C 6 H 5 ) 4 ] 2 Sb 2 S 15 2(C 3 N 2 H 6 ) and their crystal structures were determi