New approach to the synthesis of fenestrane derivatives
โ Scribed by V. A. Smit; S. M. Bukhanyuk; A. S. Shashkov; Yu. T. Struchkov; A. I. Yanovskii
- Book ID
- 112444177
- Publisher
- Springer
- Year
- 1988
- Tongue
- English
- Weight
- 129 KB
- Volume
- 37
- Category
- Article
- ISSN
- 1573-9171
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The synthesis of tetracyclo15.4.1.0 4~12.0g~121dodecan-6-one JJ via an intramolecular photocycloadditlon, its reduction to the hydrocarbon Q, and its ring-contraction to tetracyclo-[4 4 1 03\*11.09JI . . . lundecane derivative g is described. The hydrocarbon tetracyclo13.3.1.03~g.07~glnonane ,I, kno
## Abstract For Abstract see ChemInform Abstract in Full Text.
## j%Flaoropyrrole derivatives are qnthesized in high yields by the reaction of a,a-difluoro-+odo-y(electron-witMrawlng-group)-slrbsrirvred ketones and ammo&~ hy&ozdde a~ mom tempcrorurc; providing a new, simple. and q@Icient waethod for the synthesis Qj3-jiuorinatedpyrrole tings. A possible wucha