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Synthesis of (4.5.5.5]fenestrane and a [4.4.5.5]fenestrane derivative

✍ Scribed by William G. Dauben; Daniel M. Walker

Publisher: Elsevier Science
Year: 1982
Tongue: French
Weight: 230 KB
Volume: 23
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)86928-2

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✦ Synopsis

The synthesis of tetracyclo15.4.1.0 4~12.0g~121dodecan-6-one JJ via an intramolecular photocycloadditlon, its reduction to the hydrocarbon Q, and its ring-contraction to tetracyclo-[4 4 1 03*11.09JI . . . lundecane derivative g is described. The hydrocarbon tetracyclo13.3.1.03~g.07~glnonane ,I, known as [4.4.4.4lfenestrane, or simply windowpane, has been the subject of several recent discussions' and synthetic studies.* The synthetic work has resulted in the synthesis of 15.5.

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