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N-Heterocyclic Carbene Based Ruthenium-Catalyzed Direct Amide Synthesis from Alcohols and Secondary Amines: Involvement of Esters

✍ Scribed by Chen, Cheng; Zhang, Yao; Hong, Soon Hyeok

Book ID
120432047
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
487 KB
Volume
76
Category
Article
ISSN
0022-3263

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N-Heterocyclic Carbene Based Ruthenium-C
N-Heterocyclic Carbene Based Ruthenium-Catalyzed Direct Amide Synthesis from Alcohols and Secondary Amines: Involvement of Esters
✍ Chen, Cheng; Zhang, Yao; Hong, Soon Hyeok πŸ“‚ Article πŸ“… 2011 πŸ› American Chemical Society 🌐 English βš– 487 KB

A well-defined N-heterocyclic carbene based ruthenium complex was developed as a highly active precatalyst for the direct amide synthesis from alcohols and secondary amines. Notably, reaction of 1-hexanol and dibenzylamine afforded 60% of the corresponding amide using our catalytic system, while no