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Dehydrogenative Synthesis of Imines from Alcohols and Amines Catalyzed by a Ruthenium N-Heterocyclic Carbene Complex

✍ Scribed by Maggi, Agnese; Madsen, Robert

Book ID
120280060
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
368 KB
Volume
31
Category
Article
ISSN
0276-7333

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A well-defined N-heterocyclic carbene based ruthenium complex was developed as a highly active precatalyst for the direct amide synthesis from alcohols and secondary amines. Notably, reaction of 1-hexanol and dibenzylamine afforded 60% of the corresponding amide using our catalytic system, while no