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ChemInform Abstract: N-Heterocyclic Carbene Based Ruthenium-Catalyzed Direct Amide Synthesis from Alcohols and Secondary Amines: Involvement of Esters.

✍ Scribed by Cheng Chen; Yao Zhang; Soon Hyeok Hong

Book ID
112042497
Publisher
John Wiley and Sons
Year
2012
Weight
45 KB
Volume
43
Category
Article
ISSN
0931-7597

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N-Heterocyclic Carbene Based Ruthenium-C
N-Heterocyclic Carbene Based Ruthenium-Catalyzed Direct Amide Synthesis from Alcohols and Secondary Amines: Involvement of Esters
✍ Chen, Cheng; Zhang, Yao; Hong, Soon Hyeok πŸ“‚ Article πŸ“… 2011 πŸ› American Chemical Society 🌐 English βš– 487 KB

A well-defined N-heterocyclic carbene based ruthenium complex was developed as a highly active precatalyst for the direct amide synthesis from alcohols and secondary amines. Notably, reaction of 1-hexanol and dibenzylamine afforded 60% of the corresponding amide using our catalytic system, while no