There are extensive reports on the deamlnatlone of a-amino aclde and their esters, and the deaminatione of a-amino acids are generally recognized to occur with retention of configuration due to the participation of the neighboring carboxylate group, while the deaminatlons of a-amino acid eetere proc
N-Cinnamoyl-l-valine methyl ester
✍ Scribed by Bornaghi, Laurent F. ;Poulsen, Sally-Ann ;Healy, Peter C. ;White, Alan R.
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 186 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The crystal structure of the title compound, C 15 H 19 NO 3 , shows that the overall molecular conformation, which is approximately planar, is stabilized by intermolecular N-HÁ Á ÁO hydrogen-bonding interactions.
📜 SIMILAR VOLUMES
## Experimental An equimolar mixture of 4 H -bromomethylbiphenyl-2-carbonitrile (1.36 g, 0.005 mol), l-valine methyl ester (0.655 g, 0.005 mol) and
The title compound, C 7 H 13 NO 3 , was prepared by acetylation of l-valine. The C(carbonyl)ÐN bond length is 1.324 (2) A Ê , which corresponds to the CÐN bond length of a typical acylamine group.