Structure and conformation of n- (t-butoxycarbonyl)-l-valine-l-phenylalanine-methyl ester (Boc-Val-Phe-OMe)
β Scribed by A. Nallini; K. Saraboji; M. N. Ponnuswamy; S. B. Katti
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 148 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0232-1300
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## Abstract The peptide NβAcβdehydroβPheβLβValβLβValβOCH~3~ (C~22~H~31~N~3~O~5~) was synthesized by the usual workup procedure and finally by coupling the NβAcβdehydroβPheβLβValβOH to valine methyl ester. It was crystallized from its solution in acetonitrileβwater mixture at 4Β°C. The crystals belon
The peptide N-Boc-L-Pro-dehydro-Phe-L-Gly-OH was synthesized by the usual workup procedure and finally coupling the N-Boc-L-Pro-dehydro-Phe to glycine. The geptide crystallizes monoclinic space group P2: with a = 8.951( ) A, b = 5.677(6) A, c = 21.192(11) A, p = 96.97(4)', V = 1069(1) A3, Z = 2, d,
The peptide N-Boc-L-Gly-dehydro-Phe-NHCH, was synthesized by the combination of N-Boc-L-Gly-dehydro-Phe azlactone and pethylamine. Th? peptide crystalliqes in orthorhoybic space group P2,2121 with a = 5.679( 2) A, b = 16.423(9) A, c = 19.198(10) A, V = 1791(2) A3, 2 = 4, d m = 1.212(5) Mg m-,, dc =