Single-crystal X-ray study T = 250 K Mean '(C±C) = 0.004 A Ê R factor = 0.056 wR factor = 0.156 Data-to-parameter ratio = 15.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
N-{3-Isopropoxy-4-methoxy-2-[(E)-1-propenyl]benzyl}(phenyl)methanesulfonamide
✍ Scribed by Otterlo, Willem A. L. van ;Panayides, Jenny-Lee ;Fernandes, Manuel A.
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 452 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
The crystal structure of the title compound, C 21 H 27 NO 4 S, con®rms the presence of a monoalkylated sulfonamide group and that the propenyl group of the synthetic precursor has isomerized into the more thermodynamically favoured styrene. Analysis of the structure reveals that it is held together by a network of NÐHÁ Á ÁO, CÐHÁ Á ÁO S and %±% interactions.
📜 SIMILAR VOLUMES
The title compound, C 22 H 18 N 2 O 3 , was synthesized by oxidation of benzoic acid (3-benzyloxy-4-methoxybenzylidene)hydrazide with bis(trifluoroacetoxy)iodobenzene in chloroform at room temperature.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.044 wR factor = 0.124 Data-to-parameter ratio = 7.8 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.