In the title compound, C~17~H~12~ClN~3~O~5~, the benzene rings are twisted out of the central –C~ar~–C–C(–CN)–C(=O)–N–plane. The dihedral angles between this plane and the aromatic planes are 31.2 (4) and 4.8 (3)°. The C=C double bond is in an __E__ configuration.
N-(2-Bromo-3-pyridyl)-3-methylbut-2-enamide
✍ Scribed by Walji, Dhiran V. B. ;Storey, John M. D. ;Harrison, William T. A.
- Book ID
- 104490265
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 197 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title molecule, C 21 H 16 Br 2 N 2 O 2 S, the S atom shows a distorted tetrahedral geometry. The sulfonylphenyl and bromophenyl rings are oriented almost perpendicular to the indole ring system, with dihedral angles of 84.2 (5) and 85.0 (5) , respectively. The molecular structure is stabilize
A series of derivatives of 2-hydroxy-3methylbut-2-and -3-enenitrile, including po-glucopyranosides, were obtained and their 'H and 13CNMR spectra were investigated. The spectra were assigned using lanthanide-induced shifts, NOE difference spectroscopy and deuterium labelling. 'HNMR 13CNMR 2-hydroxy-
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