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2-Bromo-N-[3-bromo-N-(phenyl­sulfonyl)­indol-2-yl­methyl]­aniline

✍ Scribed by Govind, M. M. ;Govindaraj, J. ;Rajakannan, V. ;Velmurugan, D. ;Kim, Moon-Jib ;Srinivasan, P. C. ;Kannadasan, S.

Publisher
International Union of Crystallography
Year
2002
Tongue
English
Weight
188 KB
Volume
58
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title molecule, C 21 H 16 Br 2 N 2 O 2 S, the S atom shows a distorted tetrahedral geometry. The sulfonylphenyl and bromophenyl rings are oriented almost perpendicular to the indole ring system, with dihedral angles of 84.2 (5) and 85.0 (5) , respectively. The molecular structure is stabilized by CÐHÁ Á ÁO and NÐHÁ Á ÁBr intramolecular hydrogen bonds.

📜 SIMILAR VOLUMES

2-Bromo-N-[3-bromo-1-(phenyl­sulfonyl)­i
2-Bromo-N-[3-bromo-1-(phenyl­sulfonyl)­indol-2-yl­methyl]-4-methyl­aniline
✍ Govind, M. M. ;Govindaraj, J. ;Rajakannan, V. ;Velmurugan, D. ;Kim, Moon-Jib ;Sr 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 208 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.014 A Ê R factor = 0.056 wR factor = 0.135 Data-to-parameter ratio = 13.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

3-Bromo-2-bromo­methyl-1-phenyl­sulfonyl
3-Bromo-2-bromo­methyl-1-phenyl­sulfonyl-1H-indole
✍ Sakthivel, P. ;Sethusankar, K. ;Sankar, P. Jai ;Joseph, P. S. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 160 KB

The phenyl ring in the title compound, C~15~H~11~Br~2~NO~2~S, makes a dihedral angle of 81.8 (1)° with the mean plane of the indole system. The molecular structure is stabilized by C—H...O hydrogen bonds.

Ethyl N-(5-bromo-3-phenyl­indol-2-yl)­ca
Ethyl N-(5-bromo-3-phenyl­indol-2-yl)­carbamate
✍ Mruthyunjayaswamy, B. H. M. ;Ijare, Omkar B. ;Jadegoud, Y ;Ray Chaudhuri, A. ;Gu 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 342 KB

The crystal structure of the title compound, C 17 H 15 BrN 2 O 2 , has been determined at room temperature. The indole moiety is essentially planar and the structure is stabilized by intra-and intermolecular NÐHÁ Á ÁO hydrogen bonds.

3-Bromo-2-(2-bromo-4,5-dimethoxy­benz­yl
3-Bromo-2-(2-bromo-4,5-dimethoxy­benz­yl)-1-phenyl­sulfonyl-1H-indole
✍ Ravishankar, T. ;Chinnakali, K. ;Arumugam, N. ;Srinivasan, P. C. ;Usman, Anwar ; 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 439 KB

In the title compound, C 19 H 15 BrN 2 O 4 S, the orientations of the phenylsulfonyl and 2-bromo-4,5-dimethoxybenzyl substituents with respect to the indole moiety are influenced by intramolecular C-HÁ Á ÁO and C-HÁ Á ÁBr interactions. The sulfonyl-bound phenyl ring forms a dihedral angle of 86.9 (1