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3-(1,3-Benzodioxol-5-yl)-N-(2-methyl­prop­yl)prop-2-enamide (fagaramide)

✍ Scribed by Bohle, D. Scott ;Fotie, Jean

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
88 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, C 14 H 17 NO 3 , is a natural product which can be isolated from many plants. In the molecule, the amide group adopts a planar Z geometry.

📜 SIMILAR VOLUMES

3-(1,3-Benzodioxol-5-yl)-1-phenyl­prop-2
3-(1,3-Benzodioxol-5-yl)-1-phenyl­prop-2-en-1-one
✍ Yathirajan, H. S. ;Sarojini, B. K. ;Narayana, B. ;Bindya, S. ;Bolte, Michael 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 181 KB

In the title biologically active compound, C 16 H 12 O 3 , the central C C double bond is trans configured. The molecule consists of two essentially planar parts which are twisted by 26.89 (5) with respect to each other.

(2E)-3-(1,3-Benzodioxol-5-yl)-1-(4-bromo
(2E)-3-(1,3-Benzodioxol-5-yl)-1-(4-bromo­phen­yl)prop-2-en-1-one
✍ Harrison, William T. A. ;Bindya, S. ;Yathirajan, H. S. ;Sarojini, B. K. ;Narayan 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 267 KB

In the approximately planar molecule of the title compound, C 16 H 11 BrO 3 , the dihedral angle between the two benzene rings is 6.61 (18) . This compound crystallizes in a centrosymmetric space group, so it does not display a second-harmonic generation response.

3-(1,3-Benzodioxol-5-yl)-2-bromo-1-(2,4-
3-(1,3-Benzodioxol-5-yl)-2-bromo-1-(2,4-dichloro-5-fluorophenyl)prop-2-en-1-one
✍ Dhanasekaran, V. ;Gayathri, D. ;Velmurugan, D. ;Ravikumar, K. ;Karthikeyan, M. S 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 122 KB

In the title molecule, C 16 H 8 BrCl 2 FO 3 , the dioxole ring adopts a twist conformation. The molecules are linked into a chain along the c axis by C-HÁ Á ÁÁO intermolecular interactions, and adjacent chains are crosslinked viainteractions.

(E)-3-(1,3-Benzodioxol-5-yl)-1-(2-hydr­o
(E)-3-(1,3-Benzodioxol-5-yl)-1-(2-hydr­oxy-4,6-dimethoxy­phen­yl)prop-2-en-1-one
✍ Gao, Shan ;Ng, Seik Weng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 122 KB

In the title compound, C 18 H 16 O 6 , a herbicide, the dioxole ring adopts a flattened envelope conformation. The two aromatic rings at either end of the propenone linkage are almost coplanar with it. The hydroxy group is involved in an intramolecular O-HÁ Á ÁO hydrogen bond.