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Muonium chemistry: quantum mechanical calculations for the collinear reaction Mu + F2(ν = 0) → MuF(ν′ ⩽ 3) + F

✍ Scribed by J.N.L. Connor; W. Jakubetz; J. Manz

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
620 KB
Volume
45
Category
Article
ISSN
0009-2614

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✦ Synopsis

Quantum mechanica1 transition probabïlities have been calculated for the collinear reaction hfu + F~(u = 0) -+ MuF(u' G 3) + F by the state pa*& sum method. The "best" extended LEPS surface no. 11 of Jonxthan et al. for the tl + F2 reaction bas been used. Approximately 40% of the available reaction energy goes into the product vibrationai degree of freedom, with the most populated state beïng v' = 1. Collinear rate constants have ako been calculated. At 300 R tunnelling is very important, hut at 900 K classically allowed processes are dolninant.

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