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Integral and state-to-state cross sections for the reaction D + H2(νf) → HD(νf) + H: A quantum mechanical study within the infinite order sudden approximation

✍ Scribed by N. Abusalbi; D.J. Kouri; Y. Shima; M. Baer

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
455 KB
Volume
105
Category
Article
ISSN
0009-2614

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✦ Synopsis

&I lbis paper are presented quantum mechanical I-initial and I-average cross sections and rate constants for the reactions: D + Hz(Ui = 0. 1) -HD(ur = 0. 1) + H. The calculations were done employing the iufiuile order sudden approximation It was found that the I-average total cross sections overlap very nicely with the available cJas.sical cross sections As for rate constants a reasonably good tit was found with avaiktble experimenral raultr * Support under Nationaf Science Foundation grant CHEX2-15317 isgratefully acknowledged * Acknowledgement IS made to the donos of the Petroleum Research Fund_ administered by the American Chemicai Society, for partial support of this research * Visiting Professor,

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