Integral reactive quantum-mechanIcal cross secfions and product vibrational dlstriiuhons are presented for the r + Hz system. The calculations were made within the mfmite order sudden approximahon (IOSA) formahsm and the results are compared wllh expenmental data and results obtamcd with other treat
Integral and differential cross sections for the heavy-light-heavy cihci reaction. A quantum mechanical study within the infinite order sudden approximation
โ Scribed by N. Abusalbi; S.-H. Kim; D.J. Kouri; M. Baer
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 285 KB
- Volume
- 112
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
In this communication WC present qumtum mCch.miCal intgrJ1 and diffcrcntial cross sections for the rwction IICl(y-= 0) + Cl' -IiCl' f CI The cdlcuhtions cmploycd the the inl-mitc order sudden approtimation. The characteristic osciUations cncountcrcd in collinear calculations \ere still apptrcnt in tlucc dimcnsiom.
๐ SIMILAR VOLUMES
&I lbis paper are presented quantum mechanical I-initial and I-average cross sections and rate constants for the reactions: D + Hz(Ui = 0. 1) -HD(ur = 0. 1) + H. The calculations were done employing the iufiuile order sudden approximation It was found that the I-average total cross sections overlap
Integral reactive classical cross sections and product vibratronal distrrbutions are presented for the F + Ha system The calculations were made within the infinite order sudden appro.umatron (IOSA) and the results compared with recent quantum-mechamcal IOSA and exact classical results.