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A classical reactive study within the infinite order sudden approximation: integral cross sections for the reactions F + H2vi = 0) → HF(vf = 0,1,2,3) + H

✍ Scribed by Julius Jellinek; Michael Baer

Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
395 KB
Volume
82
Category
Article
ISSN
0009-2614

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✦ Synopsis

Integral reactive classical cross sections and product vibratronal distrrbutions are presented for the F + Ha system The calculations were made within the infinite order sudden appro.umatron (IOSA) and the results compared with recent quantum-mechamcal IOSA and exact classical results.

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In this communication WC present qumtum mCch.miCal intgrJ1 and diffcrcntial cross sections for the rwction IICl(y-= 0) + Cl' -IiCl' f CI The cdlcuhtions cmploycd the the inl-mitc order sudden approtimation. The characteristic osciUations cncountcrcd in collinear calculations \\ere still apptrcnt in