Integral reactive classical cross sections and product vibratronal distrrbutions are presented for the F + Ha system The calculations were made within the infinite order sudden appro.umatron (IOSA) and the results compared with recent quantum-mechamcal IOSA and exact classical results.
Integral cross sections for the reaction F + H2, (vi = 0) → HF(vf = 0,1,2,3) + H: a quantum-mechanical calculation within the infinite order sudden approximation
✍ Scribed by J. Jellinek; M. Baer; V. Khare; D.J. Kouri
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 445 KB
- Volume
- 75
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Integral reactive quantum-mechanIcal cross secfions and product vibrational dlstriiuhons are presented for the r + Hz system. The calculations were made within the mfmite order sudden approximahon (IOSA) formahsm and the results are compared wllh expenmental data and results obtamcd with other treatments_
📜 SIMILAR VOLUMES
&I lbis paper are presented quantum mechanical I-initial and I-average cross sections and rate constants for the reactions: D + Hz(Ui = 0. 1) -HD(ur = 0. 1) + H. The calculations were done employing the iufiuile order sudden approximation It was found that the I-average total cross sections overlap
In this communication WC present qumtum mCch.miCal intgrJ1 and diffcrcntial cross sections for the rwction IICl(y-= 0) + Cl' -IiCl' f CI The cdlcuhtions cmploycd the the inl-mitc order sudden approtimation. The characteristic osciUations cncountcrcd in collinear calculations \\ere still apptrcnt in
in final form 17 Jzmuxy 19S3 \'elocrf~ -scatterms angle intenslty mqs for the 1: + Il,(u = O;] = 0) -1'11( r: = 1.3; j') + II reaction are predicted from ~1rr~ntur"-nrcclranic~l I\_-consening calculations. The extent of the s/xi/r in the angular distribution from barksntteriq at 1-S hc.d,!molr 10 si
A close-coupling calculation of integral cross sections for the reaction F + Hz (u= 0, j= 0) +FH ( v'f ) + H has been performed in the threshold energy range using hyperspherical coordinates, The convergence of partial reaction probabilities with respect to a,, the maximum magnitude of the total ang