✦ LIBER ✦

Collinear quantum mechanical probabilities and rate constants for the Br + HCl(ν = 2, 3, 4) reaction using hyperspherical coordinates

✍ Scribed by Jack A. Kaye; Aron Kuppermann

Publisher: Elsevier Science
Year: 1982
Tongue: English
Weight: 449 KB
Volume: 92
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(82)83653-1

No coin nor oath required. For personal study only.

✦ Synopsis

Calculations of quantum mechanical probabilities and rate constants for the collinear reaction Br + HC1 (o = 2, 3,4) BrH + C1, Br + HCI(o' < o) were performed using hyperspherical coordinates. Removal of vibrationaUy excited HC1 proceeds mainly by reaction to a nearly degenerate HBr state. Processes for which a large change in the internal energy occurs have low probabilities.