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Multicomponent C-Alkylation Reactions of Aromatic Aldimines with Trialkylboranes Reagents

✍ Scribed by María Valpuesta; Carmen Muñoz; Amelia Díaz; Gregorio Torres; Rafael Suau

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
236 KB
Volume
2010
Category
Article
ISSN
1434-193X

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Organoborane Reagents in the C-Alkylatio
Organoborane Reagents in the C-Alkylation of Aromatic Aldimines
✍ María Valpuesta; Carmen Muñoz; Amelia Díaz; Rafael Suau; Gregorio Torres 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 94 KB

## Abstract The reaction of an aldimine with dicyclohexylboron chloride in the presence of hydrogen peroxide gives __N__‐[cyclohexyl(aryl)methyl]arylamines **2** in good yields via oxidized imine–borane complexes. The amines can also be obtained by a three‐component reaction involving an arenecarba