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ChemInform Abstract: Organoborane Reagents in the C-Alkylation of Aromatic Aldimines.

✍ Scribed by Maria Valpuesta; Carmen Munoz; Amelia Diaz; Rafael Suau; Gregorio Torres

Publisher
John Wiley and Sons
Year
2008
Weight
37 KB
Volume
39
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

Organoborane Reagents in the C-Alkylatio
Organoborane Reagents in the C-Alkylation of Aromatic Aldimines
✍ MarΓ­a Valpuesta; Carmen MuΓ±oz; Amelia DΓ­az; Rafael Suau; Gregorio Torres πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 94 KB

## Abstract The reaction of an aldimine with dicyclohexylboron chloride in the presence of hydrogen peroxide gives __N__‐[cyclohexyl(aryl)methyl]arylamines **2** in good yields via oxidized imine–borane complexes. The amines can also be obtained by a three‐component reaction involving an arenecarba