Comparison of the dynamics of the reactions of Ba with aromatic halides and alkyl halides LIF studies of the reactions of Ba with C6H5X (X Cl, Br, I)
✍ Scribed by Ke-Li Han; Guo-Zhong He; Nan-Quan Lou
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 455 KB
- Volume
- 203
- Category
- Article
- ISSN
- 0009-2614
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## Abstract The gas‐phase ion‐molecule chemistry of exohedrally bound C~60~Rh^+^ with CH~3~X, C~6~H~5~X (X = Cl, Br, and I) and CH~2~I~2~ is studied using Fourier transform ion cyclotron resonance mass spectrometry. Reactions with CH~3~I and CH~2~I~2~ yield the buckminsterfullerene derivatives, C~6
The title compounds were obtained by annealing powders of the alkaline-earth metaperrhenates \(M\left(\mathrm{ReO}_{4}\right)_{2} \cdot \mathrm{H}_{2} \mathrm{O}\) with an excess of the corresponding alkaline-earth halides in open alumina crucibles. The strontium compounds are new. They crystallize