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Magnitude and Origin of the Attraction and Directionality of the Halogen Bonds of the Complexes of C6F5X and C6H5X (X=I, Br, Cl and F) with Pyridine

✍ Scribed by Dr. Seiji Tsuzuki; Dr. Akihiro Wakisaka; Dr. Taizo Ono; Prof. Takaaki Sonoda


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
388 KB
Volume
18
Category
Article
ISSN
0947-6539

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✍ Zel-Ho Choi; Wieland Tyrra; Arnold Adam πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 German βš– 127 KB πŸ‘ 2 views

In(C 6 F 5 ) 3 Β΄CH 3 CN and In(C 6 F 5 ) 3 Β΄glyme were synthesized from InCl 3 and Cd(C 6 F 5 ) 2 in CH 3 CN or glyme in 43% and 35% yield, respectively. Replacement of CH 3 CN or (C 2 H 5 ) 2 O by DMAP yielded the corresponding 1 : 1-adduct. [PNP][In(C 6 F 5 ) 4 ] was best prepared from the corres