Rhodium-Catalyzed ortho-Alkylation of Aromatic Aldimines and Ketimines with Olefins via C—H Bond Activation
✍ Scribed by Adam J. Preston; Amanda L. Hofacker; Jon R. Parquette
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 56 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access the actual ChemInform Abstract, please click on HTML or PDF.
Described herein is the Rh I -catalyzed ortho-alkylation of aromatic ketimines or ketones with olefins. This method showed high reactivity and selectivity to monoalkylation for a variety of olefins including 1-alkenes with an allylic proton, a,w-dienes, and internal olefins. For a mechanistic study,