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Rhodium-Catalyzed ortho-Alkylation of Aromatic Aldimines and Ketimines with Olefins via C—H Bond Activation

✍ Scribed by Adam J. Preston; Amanda L. Hofacker; Jon R. Parquette


Publisher
John Wiley and Sons
Year
2003
Weight
56 KB
Volume
34
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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Chelation-Assisted RhI-Catalyzed ortho-A
✍ Chul-Ho Jun; Choong Woon Moon; Jun-Bae Hong; Sung-Gon Lim; Kwan-Yong Chung; Yeon 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 161 KB 👁 1 views

Described herein is the Rh I -catalyzed ortho-alkylation of aromatic ketimines or ketones with olefins. This method showed high reactivity and selectivity to monoalkylation for a variety of olefins including 1-alkenes with an allylic proton, a,w-dienes, and internal olefins. For a mechanistic study,