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Rhodium-Catalyzed Alkylation of Terephthaldialdimine with Terminal Alkenes via C—H Bond Activation.

✍ Scribed by Yeong-Gweon Lim; Bon Tak Koo


Publisher
John Wiley and Sons
Year
2006
Weight
18 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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ChemInform Abstract: Regioselective Alky
✍ Y.-G. LIM; J.-B. KANG; Y. H. KIM 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views

Regioselective Alkylation of 2-Phenylpyridines with Terminal Alkenes via C-H Bond Activation by a Rhodium Catalyst. -Rh(I)-catalyzed reaction of 2-phenylpyridines with terminal alkenes provides regioselectively or even exclusively ortho-alkylated products of the anti-Markovnikov-type (cf. (III), (VI