Rhodium-Catalyzed Alkylation of Terephthaldialdimine with Terminal Alkenes via C—H Bond Activation.
✍ Scribed by Yeong-Gweon Lim; Bon Tak Koo
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 18 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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Regioselective Alkylation of 2-Phenylpyridines with Terminal Alkenes via C-H Bond Activation by a Rhodium Catalyst. -Rh(I)-catalyzed reaction of 2-phenylpyridines with terminal alkenes provides regioselectively or even exclusively ortho-alkylated products of the anti-Markovnikov-type (cf. (III), (VI
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