Molybdenum(II)-catalyzed allylic substitution

✍ Scribed by Andrei V. Malkov; Ian Baxendale; Darren J. Mansfield; Pavel Kočovsky

• Book ID: 104257408
• Publisher: Elsevier Science
• Year: 1997
• Tongue: French
• Weight: 243 KB
• Volume: 38
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(97)01052-6

✦ Synopsis

The new Mo(II) triflate complex 5 has been found to catalyze the C-C bond forming allylic substitution with silyl enol ethers derived from [i-dicarbonyls (e.g., 6 + 12 ---> 14) and from simple ketones (e.g., 6 + 13 ---> 16) as nucleophiles.