𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Molybdenum(II)- and Tungsten(II)-Catalyzed Allylic Substitution

✍ Scribed by Malkov, Andrei V.; Baxendale, Ian R.; Dvořák, Dalimil; Mansfield, Darren J.; Kočovský, Pavel

Book ID
126874777
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
457 KB
Volume
64
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Molybdenum(II)-catalyzed allylic substit
Molybdenum(II)-catalyzed allylic substitution
✍ Andrei V. Malkov; Ian Baxendale; Darren J. Mansfield; Pavel Kočovsky 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 243 KB

The new Mo(II) triflate complex 5 has been found to catalyze the C-C bond forming allylic substitution with silyl enol ethers derived from [i-dicarbonyls (e.g., 6 + 12 ---> 14) and from simple ketones (e.g., 6 + 13 ---> 16) as nucleophiles.