𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Asymmetric molybdenum(0)-catalyzed allylic substitution

✍ Scribed by Andrei V. Malkov; Paul Spoor; Victoria Vinader; Pavel Kočovský

Book ID
104211551
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
82 KB
Volume
42
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Molybdenum(II)-catalyzed allylic substit
Molybdenum(II)-catalyzed allylic substitution
✍ Andrei V. Malkov; Ian Baxendale; Darren J. Mansfield; Pavel Kočovsky 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 243 KB

The new Mo(II) triflate complex 5 has been found to catalyze the C-C bond forming allylic substitution with silyl enol ethers derived from [i-dicarbonyls (e.g., 6 + 12 ---> 14) and from simple ketones (e.g., 6 + 13 ---> 16) as nucleophiles.