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Molybdenum(II)-catalyzed alkylation of electron-rich aromatics with allylic acetates

✍ Scribed by Andrei V. Malkov; Stuart L. Davis; William L. Mitchell; Pavel Kočovský

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
196 KB
Volume
38
Category
Article
ISSN
0040-4039

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Highly Efficient Molybdenum(II)-Catalyze
Highly Efficient Molybdenum(II)-Catalyzed Intramolecular Allylic Alkylation of Arenes
✍ Marco Bandini; Astrid Eichholzer; Peter Kotrusz; Achille Umani-Ronchi 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 193 KB 👁 1 views

## Abstract The Friedel–Crafts‐type intramolecular allylic alkylation of simple arenes is performed in the presence of a catalytic amount of [Mo(II) (CO)~4~Br~2~]~2~ (2.5 mol%). The moisture‐tolerant protocol provided a mild and direct access to a large library of functionalized 4‐vinyl‐1,2,3,4‐tet