Asymmetric IrI-Catalysed Allylic Alkylat
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BjΓΆrn Bartels; Cristina GarcΓa-Yebra; GΓΌnter Helmchen
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Article
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2003
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John Wiley and Sons
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English
β 150 KB
## Abstract Monodentate phosphorus amidites derived from 2,2β²βbinaphthol and a variety of chiral amines were employed as ligands in Ir^I^βcatalysed allylic alkylations of unsymmetrically substituted allylic acetates. The enantioβ and regioselectivities of these reactions were investigated. Phosphor