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Asymmetric IrI-Catalyzed Allylic Alkylation of Monosubstituted Allylic Acetates with Phosphorus Amidites as Ligands.

✍ Scribed by Bjoern Bartels; Cristina Garcia-Yebra; Guenter Helmchen


Publisher
John Wiley and Sons
Year
2003
Weight
207 KB
Volume
34
Category
Article
ISSN
0931-7597

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Asymmetric IrI-Catalysed Allylic Alkylat
✍ BjΓΆrn Bartels; Cristina GarcΓ­a-Yebra; GΓΌnter Helmchen πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 150 KB

## Abstract Monodentate phosphorus amidites derived from 2,2′‐binaphthol and a variety of chiral amines were employed as ligands in Ir^I^‐catalysed allylic alkylations of unsymmetrically substituted allylic acetates. The enantio‐ and regioselectivities of these reactions were investigated. Phosphor