ChemInform Abstract: Diphosphites as a Promising New Class of Ligands in Pd-Catalyzed Asymmetric Allylic Alkylation.
β Scribed by Montserrat Dieguez; Susanna Jansat; Montserrat Gomez; Aurora Ruiz; Guillermo Muller; Carmen Claver
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 28 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
Among several new ligands the (S,S)-BOP ligand affords the best results of regio-and stereoselectivity in the allylic alkylations of 1-and 3-aryl-2-propenyl acetates such as (I) and (V). Alkyl substituted analogues like (VI) react with distinctly lower selectivities in the presence of this ligand. -
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