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ChemInform Abstract: New Ligands for Regio- and Enantiocontrol in Pd-Catalyzed Allylic Alkylations.

✍ Scribed by R. PRETOT; A. PFALTZ

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Among several new ligands the (S,S)-BOP ligand affords the best results of regio-and stereoselectivity in the allylic alkylations of 1-and 3-aryl-2-propenyl acetates such as (I) and (V). Alkyl substituted analogues like (VI) react with distinctly lower selectivities in the presence of this ligand. -

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