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ChemInform Abstract: Memory Effects in Pd-Catalyzed Allylic Alkylations

✍ Scribed by Giovanni Poli; Carlo Scolastico

Publisher: John Wiley and Sons
Year: 2010
Weight: 24 KB
Volume: 31
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200011283

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## Abstract For Abstract see ChemInform Abstract in Full Text.

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Among several new ligands the (S,S)-BOP ligand affords the best results of regio-and stereoselectivity in the allylic alkylations of 1-and 3-aryl-2-propenyl acetates such as (I) and (V). Alkyl substituted analogues like (VI) react with distinctly lower selectivities in the presence of this ligand. -