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Memory Effects in Palladium-Catalyzed Allylic Alkylations of 2-Cyclohexen-1-yl Acetate

✍ Scribed by Nina Svensen; Peter Fristrup; David Tanner; Per-Ola Norrby

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
422 KB
Volume
349
Category
Article
ISSN
1615-4150

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Highly Diastereoselective Synthesis of 2,6-Di[1-(2-alkylaziridin-1-yl)alkyl]pyridines, Useful Ligands in Palladium-Catalyzed Asymmetric Allylic Alkylation
✍ Diego Savoia; Giuseppe Alvaro; Romano Di Fabio; Claudio Fiorelli; Andrea Gualand 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 238 KB 👁 1 views

## Abstract __C__~2~‐Symmetrical, enantiopure 2,6‐di[1‐(1‐aziridinyl)alkyl]pyridines (DIAZAPs) were prepared by a high‐yielding, three‐step sequence starting from 2,6‐pyridinedicarbaldehyde and (__S__)‐valinol or (__S__)‐phenylglycinol. The new compounds were tested as ligands in palladium‐catalyze