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ChemInform Abstract: New Chiral Phosphine—Amide Ligands in Palladium-Catalyzed Asymmetric Allylic Alkylations.

✍ Scribed by Takashi Mino; Kohki Kashihara; Masakazu Yamashita

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
32
Category
Article
ISSN
0931-7597

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Effective Chiral Ferrocenyl Phosphine-Th
Effective Chiral Ferrocenyl Phosphine-Thioether Ligands in Enantioselective Palladium-Catalyzed Allylic Alkylations
✍ Hong Yee Cheung; Wing-Yiu Yu; Terry T. L. Au-Yeung; Zhongyuan Zhou; Albert S. C. 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 454 KB 👁 1 views

## Abstract magnified image Chiral ferrocene‐derived phosphine‐thioether mixed donor ligands supported by heterocycles effected the palladium‐catalyzed enantioselective allylic alkylations with excellent yields and enantioselectivities (up to 96% __ee__). With cyclic and unsymmetrical allylic acet