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ChemInform Abstract: Highly Efficient Molybdenum(II)-Catalyzed Intramolecular Allylic Alkylation of Arenes.

✍ Scribed by Marco Bandini; Astrid Eichholzer; Peter Kotrusz; Achille Umani-Ronchi

Publisher
John Wiley and Sons
Year
2008
Weight
52 KB
Volume
39
Category
Article
ISSN
0931-7597

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Highly Efficient Molybdenum(II)-Catalyze
Highly Efficient Molybdenum(II)-Catalyzed Intramolecular Allylic Alkylation of Arenes
✍ Marco Bandini; Astrid Eichholzer; Peter Kotrusz; Achille Umani-Ronchi πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 193 KB πŸ‘ 1 views

## Abstract The Friedel–Crafts‐type intramolecular allylic alkylation of simple arenes is performed in the presence of a catalytic amount of [Mo(II) (CO)~4~Br~2~]~2~ (2.5 mol%). The moisture‐tolerant protocol provided a mild and direct access to a large library of functionalized 4‐vinyl‐1,2,3,4‐tet