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Molybdenum catalyzed eliminations of allylic acetates. new diene synthesis

✍ Scribed by Barry M. Trost; Mark Lautens; Brian Peterson

Book ID: 104219922
Publisher: Elsevier Science
Year: 1983
Tongue: French
Weight: 214 KB
Volume: 24
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)85945-6

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✦ Synopsis

Ally1 acetates smoothly eliminate the elements of acetic acid in the presence of O,N-bis(trimethylsilyl)acetamide and molybdenum hexacarbonyl; a simple sequence permits elaboration of saturated aldehydes into a,Bryrb-dienoates which resulted in a four step synthesis of

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