✦ LIBER ✦

Formation of a terminal conjugated diene system by the palladium catalyzed elimination reactions of allylic acetates and phenyl ethers

✍ Scribed by Jiro Tsuji; Tomio Yamakawa; Mitsumasa Kaito; Tadakatsu Mandai

Publisher: Elsevier Science
Year: 1978
Tongue: French
Weight: 201 KB
Volume: 19
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)94754-9

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✦ Synopsis

A terminal conjugated diene system is present in certain natural products.

Also it can be converted to 2-olefin or 3-olefin by selective reduction. But there appeared few synthetic methods for this system. For example, a rapidly developing coupling reaction of vinyl halides with various vinyl metal reagents catalyzed by transition metal compounds is one acceptable method.

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