Modular Furanoside Diphosphite Ligands for Pd-Catalyzed Asymmetric Allylic Substitution Reactions: Scope and Limitations
✍ Scribed by Montserrat Diéguez; Oscar Pàmies; Carmen Claver
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 409 KB
- Volume
- 347
- Category
- Article
- ISSN
- 1615-4150
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## Abstract Two new highly modular carbohydrate‐based, pseudodipeptide and thioamide ligand libraries have been synthesized for the rhodium‐ and ruthenium‐catalyzed asymmetric transfer hydrogenation (ATH) of prochiral ketones. These series of ligands can be prepared efficiently from easily accessib
## Abstract A library of furanoside phosphite‐phosphoroamidite ligands has been synthesized and screened in the palladium‐catalyzed allylic substitution reactions of several substrate types. These series of ligands can be prepared efficiently from easily accessible D‐xylose and D‐glucose. Their mod