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First Chiral Phosphoroamidite-Phosphite Ligands for Highly Enantioselective and Versatile Pd-Catalyzed Asymmetric Allylic Substitution Reactions.

✍ Scribed by Eva Raluy; Carmen Claver; Oscar Pamies; Montserrat Dieguez

Publisher
John Wiley and Sons
Year
2007
Weight
30 KB
Volume
38
Category
Article
ISSN
0931-7597

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Modular Furanoside Phosphite-Phosphoroam
Modular Furanoside Phosphite-Phosphoroamidites, a Readily Available Ligand Library for Asymmetric Palladium-Catalyzed Allylic Substitution Reactions. Origin of Enantioselectivity
✍ Eva Raluy; Oscar Pàmies; Montserrat Diéguez 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 468 KB 👁 1 views

## Abstract A library of furanoside phosphite‐phosphoroamidite ligands has been synthesized and screened in the palladium‐catalyzed allylic substitution reactions of several substrate types. These series of ligands can be prepared efficiently from easily accessible D‐xylose and D‐glucose. Their mod