In the title compound, (C 8 H 8 N 4 )[ReCl 6 ]Á2H 2 O, the Re atom occupies an inversion centre and is octahedrally coordinated by chloride anions. The cation also has an inversion centre. Various N-HÁ Á ÁO, O-HÁ Á ÁCl and C-HÁ Á ÁCl interactions help to stabilize the crystal packing.
Methyltriphenylphosphonium hexachlororhenate(IV)
✍ Scribed by Hołyńska, Małgorzata ;Korabik, Maria ;Lis, Tadeusz
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 327 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the crystal structure of the title compound, C 26 H 20 Cl 2 OP + ÁCl À , there are intermolecular CÐHÁ Á ÁO hydrogen bonds, and both intramolecular and intermolecular CÐHÁ Á ÁCl hydrogen bonds.
Single-crystal X-ray study T = 100 K Mean (C-C) = 0.004 A Some non-H atoms missing Disorder in solvent or counterion R factor = 0.032 wR factor = 0.097 Data-to-parameter ratio = 18.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 291 K Mean '(N±C) = 0.004 A Ê R factor = 0.027 wR factor = 0.063 Data-to-parameter ratio = 25.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 100 K Mean '(C±C) = 0.010 A Ê R factor = 0.055 wR factor = 0.075 Data-to-parameter ratio = 17.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.