𝔖 Bobbio Scriptorium
✦   LIBER   ✦

(2,4-Di­chloro­benzoyl­methyl)­tri­phenyl­phospho­nium chloride

✍ Scribed by Zhang, Xingguo ;Zhong, Ping ;Hu, Mao-lin ;Lin, Deqing ;Lin, Jing

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
303 KB
Volume
60
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

In the crystal structure of the title compound, C 26 H 20 Cl 2 OP + ÁCl À , there are intermolecular CÐHÁ Á ÁO hydrogen bonds, and both intramolecular and intermolecular CÐHÁ Á ÁCl hydrogen bonds.

📜 SIMILAR VOLUMES

2-[(4-tert-Butyl­phenoxy)­di­chloro­meth
2-[(4-tert-Butyl­phenoxy)­di­chloro­methyl]­phenyl di­chloro­phospho­nate
✍ Pinkus, A. G. ;Klausmeyer, Kevin K. ;Feazell, Rodney P. ;Wang, Ching T. ;Moseley 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 183 KB

The reaction of phosphorus pentachloride with p-tert-butylphenyl salicylate yielded the title compound, C 17 H 17 Cl 4 O 3 P, which was originally thought to contain a PÐOÐC heterocycle. The true molecular structure has now been established by the determination of its crystal structure.

1-(2,6-Di­fluoro­benzoyl)-3-[4-(tri­fluo
1-(2,6-Di­fluoro­benzoyl)-3-[4-(tri­fluoro­methyl)­phenyl]­urea
✍ Chen, Li ;Song, Hai-Bin ;Wang, Qing-Min ;Huang, Run-Qiu ;Shang, Jian ;Mao, Chun- 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 224 KB

All bond lengths and anlges in the title compound, C 15 H 9 F 5 N 2 O 2 , an inhibitor of chitin synthesis, are normal. The urea linkage adopts an essentially planar con®guration, with an intramolecular NÐHÁ Á ÁO hydrogen bond. Intermolecular NÐHÁ Á ÁO hydrogen bonds link two adjacent molecules into

(Benzoyl­methyl)­tri­phenyl­phospho­nium
(Benzoyl­methyl)­tri­phenyl­phospho­nium iodide: supramolecular zigzag chains via C—H⋯O hydrogen bonding stabilized by C—H⋯I interactions
✍ Baby Mariyatra, Mahimaidoss ;Kalyanasundari, Balasubramanian ;Panchanatheswaran, 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 298 KB

The title phosphonium salt, C 26 H 22 OP + ÁI À , isomorphous with (benzoylmethyl)triphenylphosphonium nitrate, exhibits both intramolecular CÐHÁ Á ÁI and intermolecular CÐHÁ Á ÁO interactions. The latter interaction leads to supramolecular parallel zigzag chains along the a axis.