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2-[(4-tert-Butyl­phenoxy)­di­chloro­methyl]­phenyl di­chloro­phospho­nate

✍ Scribed by Pinkus, A. G. ;Klausmeyer, Kevin K. ;Feazell, Rodney P. ;Wang, Ching T. ;Moseley, Charles G.

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
183 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis

The reaction of phosphorus pentachloride with p-tert-butylphenyl salicylate yielded the title compound, C 17 H 17 Cl 4 O 3 P, which was originally thought to contain a PÐOÐC heterocycle. The true molecular structure has now been established by the determination of its crystal structure.

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(2,4-Di­chloro­benzoyl­methyl)­tri­pheny
(2,4-Di­chloro­benzoyl­methyl)­tri­phenyl­phospho­nium chloride
✍ Zhang, Xingguo ;Zhong, Ping ;Hu, Mao-lin ;Lin, Deqing ;Lin, Jing 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 303 KB

In the crystal structure of the title compound, C 26 H 20 Cl 2 OP + ÁCl À , there are intermolecular CÐHÁ Á ÁO hydrogen bonds, and both intramolecular and intermolecular CÐHÁ Á ÁCl hydrogen bonds.