Single-crystal X-ray study T = 100 K Mean '(C±C) = 0.003 A Ê R factor = 0.072 wR factor = 0.155 Data-to-parameter ratio = 12.5 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Triphenyl(benzoylmethyl)phosphonium hexabromodicadmate(II): supramolecular aggregation through extensive C—H⋯Br and C—H⋯O interactions
✍ Scribed by Baby Mariyatra, Mahimaidoss ;Panchanatheswaran, Krishnaswamy ;Goeta, Andres E.
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 274 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Within and between molecules of the title compound, C 27 H 24 O 9 S 3 , there are weak CÐHÁ Á ÁO interactions which generate rings of motifs S(5), S(6), R 1 2 (5), R 2 2 (14), R 2 2 (20), R 1 2 (6) and R 2 1 (4). The supramolecular aggregation is completed by the presence of CÐHÁ Á Á% and %±% intera
Single-crystal X-ray study T = 100 K Mean '(C±C) = 0.003 A Ê R factor = 0.058 wR factor = 0.128 Data-to-parameter ratio = 13.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 120 K Mean '(C±C) = 0.004 A Ê R factor = 0.047 wR factor = 0.112 Data-to-parameter ratio = 17.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the crystal structure of the title compound, C 13 H 12 O 3 S, the dihedral angle between the mean planes of the 4-tolyl and phenyl rings is 52.6 (1) . There are weak C-HÁ Á ÁO hydrogen bonds, which generate rings of graph-set motifs R 1 2 (4) and R 2 1 (9). The supramolecular aggregation is compl