๐”– Bobbio Scriptorium
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Methyltrioxorhenium as Catalyst of a Novel Aldehyde Olefination

โœ Scribed by Prof. Dr. Wolfgang A. Herrmann; Dr. Mei Wang


Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
366 KB
Volume
30
Category
Article
ISSN
0044-8249

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๐Ÿ“œ SIMILAR VOLUMES


Methyltrioxorhenium as Catalyst for Olef
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The pronounced Lewis acidity explains the exceptional activity of the title compound as catalyst for olefin epoxidations with hydrogen peroxide. The system MTO/__t__BuOH/H~2~O~2~ transforms olefins selectively and efficiently into epoxides under very mild conditions (โˆ’30 to + 60ยฐC, but normally at r

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Unprecedented high activities and selectivities were observed in the hydroformylation of internal octenes to linear products using rhodium catalysts with rigid diphosphane ligands. Dibenzophosphole 1 and a phenoxaphosphane analogue with bite angles of 120 and 119ยฐ, respectively, are suited for this.