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Methyltrioxorhenium and Its Applications in Olefin Oxidation, Metathesis and Aldehyde Olefination

โœ Scribed by Fritz E. Kuehn; Andrea Scherbaum; Wolfgang A. Herrmann

Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

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An overview of the recent synthetic breakthroughs brought about by the discovery of new, functional group tolerant late transition metal (Rh and Ru)-based catalysts is proposed. Whereas dirhodium(II)-based complexes promote only carbene transfer reactions to olefins (i.e. olefin cyclopropanation), a